The film's story begins when Arata inadvertently touches "Hermes Apocrypha," Lilith's Grimoire. Suddenly, he is enveloped by a bright white light, and a girl appears before him. She calls herself Lilim, and treats both Arata and Lilith as her parents. At the same time she appears, something changes in the world. The forbidden Eternal Library awakens. In the Library is sealed the ultimate culmination of Alchemy, the White Demon Lord. The White Demon Lord plots to eliminate Arata and the Trinity Seven to usurp the position of Demon Lord. Bristling with untold power, the White Demon Lord attacks Arata, and triggers a desperate crisis where Arata and the Trinity Seven must save the world in this last battle. (Source: ANN)

Heavens Library to Crimson Lord brings back Arata, Lilith, and the rest of the Trinity Seven to face off against the greatest enemy in the history of the Trinity Seven; Lilith's own father, who is revealed to be the strongest Demon Lord, challenges Arata who is now a Demon Lord candidate. (Source: Avex Pictures, edited)

DVD only Extras. Junna Tōno has a twin sister named Senna. He is an ordinary student at Sakurahama Private High School. However, in the past, a traffic accident deprived him of his parents and his memory. Junna survived the accident and since then, he lived only with his sister, though he's been looked after by his relatives. His present life with Senna at the same high school is so pleasant that he can forget his severe past. However, Junna begins to recall the memories he lost in the accident. He enjoys the happy and pleasant days, but he is tossed by his past, his present, and his future. What is the truth hidden in his memory?

Hida Kizuna possesses the HHG (Heart Hybrid Gear) ability, but it is not strong enough to make him particularly important. His older sister calls him to transfer to a strategic defense school, where many of the students (many of which are large-breasted girls) use their HHG abilities to fight invaders from another world while wearing extremely skimpy pilot outfits. Kizuna's fighting ability doesn't measure up, but his sister has another plan—apparently having erotic experiences with Kizuna will allow the girls to replenish their energy or power-up. It looks like his new school life is going to be full of embarrassment. (Source: MangaHelpers)